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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 5-6: 20th International Conference on Phosphorus Chemistry (ICPC-2014)
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Original Articles

Cyclic Phosphino Amino Pyridines—Novel Instrument for Construction of Catalysts and Luminescent Materials

Andrey A. KarasikA. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Kazan, RussiaCorrespondence[email protected]
,
Elvira I. MusinaA. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russia
,
Igor D. StrelnikDepartment of Chemistry, St. Petersburg State University, Russia
,
Anna S. BaluevaA. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russia
,
Yulia H. BudnikovaA. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russia
&
Oleg G. SinyashinA. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russia
Pages 729-732 | Received 21 Aug 2014, Accepted 12 Nov 2014, Published online: 01 Jul 2015
 
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GRAPHICAL ABSTRACT

Abstract

Novel cyclic phosphino amino pyridines and their mono- and binuclear Ni(II), Cu(I), and Au(I) complexes have been obtained. It has been shown that catalytic activity of the nickel-(II) complexes in electrochemical hydrogen evolution is comparable to the best catalytic systems described to date. Novel “butterfly” type copper(I) complexes show a phosphorescent nature of emission with a lifetimes in a microsecond domain.

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