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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 5-6: 20th International Conference on Phosphorus Chemistry (ICPC-2014)
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Original Articles

Attempts to Synthesize Unsymmetrical Sodium 1,2-Diphosphacyclopentadienides

Liliya KochetkovaA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
Il’ya BezkishkoA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, RussiaCorrespondence[email protected]
,
Vasili MiluykovA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
&
Oleg SinyashinA. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
Pages 863-865 | Received 09 Sep 2014, Accepted 14 Nov 2014, Published online: 01 Jul 2015
 
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GRAPHICAL ABSTRACT

Abstract

The first attempt to synthesize nonsymmetric sodium 1,2-diphosphacyclopenta- dienides was made on the basis of reaction of cyclopropenylium bromides with tertiary phosphines and following treatment of cyclopropenyl phosphonium salts with sodium polyphosphides.

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