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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 190, 2015 - Issue 5-6: 20th International Conference on Phosphorus Chemistry (ICPC-2014)
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Original Articles

Functionalized Phosphonium Ionic Liquids: Synthesis and Application

Daria ArkhipovaInstitute of Organic and Physical Chemistry A. E. Arbuzov KSC RAS, A. Arbuzov Str. 8, 420088, Kazan, Russian Federation
,
Vadim ErmolaevInstitute of Organic and Physical Chemistry A. E. Arbuzov KSC RAS, A. Arbuzov Str. 8, 420088, Kazan, Russian FederationCorrespondence[email protected]
,
Vasili MiluykovInstitute of Organic and Physical Chemistry A. E. Arbuzov KSC RAS, A. Arbuzov Str. 8, 420088, Kazan, Russian Federation
,
Lilia NigmatullinaInstitute of Organic and Physical Chemistry A. E. Arbuzov KSC RAS, A. Arbuzov Str. 8, 420088, Kazan, Russian Federation
&
Oleg SinyashinInstitute of Organic and Physical Chemistry A. E. Arbuzov KSC RAS, A. Arbuzov Str. 8, 420088, Kazan, Russian Federation
Pages 899-901 | Received 12 Sep 2014, Accepted 20 Nov 2014, Published online: 01 Jul 2015
 
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GRAPHICAL ABSTRACT

Abstract

A series of phosphonium salts with sterically hindered cation But3P+(CH2COOEt)X− (X = Cl, BF4, N(SO2CF3)2) (1) was prepared for the first time. Palladium nanoparticles (PdNPs) stabilized by (1) showed moderate activity as catalyst in Suzuki cross-coupling reaction of bromoarenes and phenylboronic acid.

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