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Original Articles

Spectroscopic Properties of New Cerium Metal–Organic Framework Based on Phosphonate Ligands with Vinyl Functional Group

, &
Pages 959-960 | Received 29 Aug 2014, Accepted 02 Dec 2014, Published online: 01 Jul 2015
 

GRAPHICAL ABSTRACT

Abstract

Phosphonate framework structures are now known with a variety of transition metals, p-block elements as well as lanthanides.1–3 The self-assembly of such phosphonate metal organic frameworks depends on numerous synthetic parameters related to the reaction conditions: temperature, time, reactant molar ratio, pH, pressure, and structural factors, such as: nature of incorporated metal, geometry of the phosphonic acid, protonation degree, presence of other coordinating moieties on the phosphonate backbone.4,5 Cerium vinylphosphonate was obtained in our laboratories by the reaction of Ce(NO3)3.6H2O, vinyl phosphonic acid in 2:3 ratio under hydrothermal conditions.

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