Silicon-Containing metal Acetylacetonates

GRAPHICAL ABSTRACT

Abstract

The addition reaction of sulfenyl chlorides of metal acetylacetonates to vinyl-, allyl-, and cyclohexenyl-containing silanes has been studied to form silicon containing chelates of chromium(III), aluminum(III), and cobalt(III). The yields and stability of the chelates depend on the nature of the alkenyl groups and decrease in the order cyclohexeny > vinyl > allyl. The decomposition leads to elimination of chlorosilane, which depends on the stability of the silicon-carbon bond in the obtained chelates. The thermal decomposition of the monomeric chelates proceeds by elimination of chlorosilane and oxidation of the acetylacetonate group. The thermal stability decreases in the order Al > Cr > Co for all compounds, depending on the ease of conversion into the other oxidation states and on the ability of the metal to catalyze the oxidative processes. The aluminum-containing polymers have chelating properties after acidic hydrolysis.

Keywords:

• Sulfenyl chlorides of metal acetylacetonates
• silanes