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Original Articles

The deoxygenation of phosphine oxides under green chemical conditions

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Pages 359-366 | Received 18 May 2015, Accepted 25 May 2015, Published online: 17 Mar 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

The deoxygenation of different phosphine oxides is an important issue. In this minireview, the reduction of mainly cyclic phosphine oxides and triaryl derivatives is surveyed using different silanes, such as trichlorosilane, phenylsilane, tetramethyldisiloxane (TMDS) and polymethylhydrosiloxane (PMHS). The best solution is the catalyst-free microwave (MW)-assisted variation in the absence of any solvent.

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