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Original Articles

peri-interactions in naphthalenes, 16.1 An expedition into the borderland between molecular and supramolecular chemistry

Pages 381-390 | Received 22 Jun 2015, Accepted 07 Jul 2015, Published online: 17 Mar 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

The length of Pd/Pt←NMe2Ar bonds is somewhat subject to a trans effect. Otherwise, they exhibit the criteria of normal covalent bonds. It is concluded that complexes containing Pd/Pt←NR3 bonds belong to the realm of molecular rather than that of supramolecular chemistry.

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