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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Phosphorylation of natural products—Cytisine, anabasine, and camphor using click chemistry methodology

E. V. SharovaA. N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, RussiaCorrespondence[email protected]
,
G. K. GenkinaA. N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, Russia
,
N. M. VinogradovaA. N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, Russia
,
O. I. ArtyushinA. N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, Russia
,
O. I. YarovayaN. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of Siberian Branch RAS, Novosibirsk, Russia
&
V. K. BrelA. N. Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, Russia
Pages 1556-1557 | Received 12 Jul 2016, Accepted 12 Jul 2016, Published online: 02 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

Anabasine-, cytisine-, and camphor-containing azides and acetylenes were used as building blocks in copper(I) catalyzed 1,3-dipolar cycloaddition reactions with a series of acetylenes and azides via click chemistry to provide a range of anabasine, cytisine, and camphor conjugates that are substances with potential biological activity.

Funding

This work was supported by the Russian Foundation for Basic Research, project No. 15-03-00663.

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