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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Phenanthroline complexes of chromium group metals for the inner-sphere hydrophosphorylation of oxo- and thioxodienes

Anna V. PlotnikovaA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russia
,
Elena V. KolpakovaA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russia
,
Evgeny V. VasilievA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russia
,
Arcady I. KuramshinA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russia
&
Vladimir I. GalkinA.M. Butlerov Institute of Chemistry, Kazan Federal University, Kazan, RussiaCorrespondence[email protected]
Pages 1566-1567 | Received 19 Jul 2016, Accepted 19 Jul 2016, Published online: 03 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

The phenanthroline ligand can stabilize organometallic complexes having oxo- or thioxodienes in the chromium group complexes for the regioselective inner-sphere hydrophosphorylation leading to the corresponding hydroxyl- or mercaptophosphonates.

Acknowledgments

The work was performed according to the Russian Government Program of Competitive Growth of Kazan Federal University.

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