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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

10-(Aryl)phenoxarsines as ligands for design of polynuclear Cu(I) complexes

Liliya S. SattarovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia;Kazan National Research Technological University, Kazan, Russia
,
Tatiana I. WittmannA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
,
Milyausha F. GalimovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia;Kazan National Research Technological University, Kazan, Russia
,
Rustem R. MusinKazan National Research Technological University, Kazan, Russia
,
Elvira I. MusinaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, RussiaCorrespondence[email protected]
,
Andrey A. KarasikA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
&
Oleg G. SinyashinA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
 show all
Pages 1587-1588 | Received 20 Jul 2016, Accepted 20 Jul 2016, Published online: 10 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

Heteroleptic or homoleptic dinuclear complexes with stoichiometry Cu2I2L2Py2 and Cu2I2L4 are obtained by reaction of 10-(aryl)phenoxarsine ligands with copper iodide in pyridine in the equimolar ratio and in a 1 : 2 stoichiometry using non-coordinating solvent respectively. Unexpectedly only 1D polymeric complex [CuIL2]n is formed by the reaction of 10-(ethoxyphenyl)phenoxarsine with CuI in the molar ratio 1 : 2.

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