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Original Articles

New 18-membered tetrakisphosphine macrocycle and its derivatives

, , , &
Pages 1591-1592 | Received 20 Jul 2016, Accepted 20 Jul 2016, Published online: 11 Aug 2016
 

GRAPHICAL ABSTRACT

ABSTRACT

The novel 18-membered aminomethylphosphine was obtained by the reaction of 1,4-bis(2-pyridylphosphine)butane with paraformaldehyde and 4-methylbenzylamine as RSSR-isomer. Its tetraoxide and tetragold complex were obtained by the oxidation and interaction with gold chloride respectively. According to the X-Ray data the structure of oxidized product is similar to the structure of linear tetragold complex.

Funding

This work was supported by the Russian Science Foundation (grants No. 15-13-30031).

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