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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 191, 2016 - Issue 11-12: 21st International Conference on Phosphorus Chemistry (ICPC-2016)
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Original Articles

Novel phosphonium salt for paste electrode to study the redox properties of insoluble compounds

M. N. KhrizanforovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian FederationCorrespondence[email protected]
,
R. P. ShekurovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
V.V. ErmolaevA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
D. M. ArkhipovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
V. A. MiluykovA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
O. N. KataevaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
,
V. V. KhrizanforovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
&
Y. H. BudnikovaA.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian Federation
 show all
Pages 1611-1612 | Received 22 Jul 2016, Accepted 22 Jul 2016, Published online: 17 Aug 2016
 
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GRAPHICAL ABSTRACT

ABSTRACT

A new carbon paste electrode is described, which contains the room temperature ionic liquid tri(tert-butyl)(decyl)phosphonium tetrafluoroborate as a binder. The advantages of this electrode are a high conductivity, very wide electrochemical window (5.4 V from 2.7 V to −2.7 V, one of the widest ever reported for RTILs), stability in time, and reproducibility.

Funding

This research was supported by the Russian Science Foundation No. 14-23-00016.

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