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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 192, 2017 - Issue 3
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SHORT COMMUNICATION

Unexpected course of Wittig reaction when using cinnamyl aldehyde as a substrate

Monika SzymczykDepartment of Bioorganic Chemistry, Faculty of Chemistry, Wroclaw University of Science and Technology, Wroclaw, PolandCorrespondence[email protected]
Pages 264-266 | Received 06 Jul 2016, Accepted 29 Sep 2016, Published online: 03 Jan 2017
 
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GRAPHICAL ABSTRACT

ABSTRACT

When trans-cinnamyl aldehyde was used as a substrate of the Wittig reaction, instead of the olefination product, formation of four products with (E)-1,3-diphenylprop-2-en-1-ol and cinnamyl alcohol was observed being quite unexpected ones. The possible mechanism of this unusual reaction has been considered.

Funding

This research was supported by grant 2011/01/N/ST5/05545 from National Science Centre.

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