ABSTRACT
In this paper, we describe thiocyanation as well as chlorination of selected allenylphosphonates/allenyl phosphine oxide, using ammonium thiocaynate or (OCH2CMe2CH2O)PNCS (for thiocyanation) or oxalyl chloride/AgNO3 for chlorination. The resulting products are vinyl (thiocyanato)phosphonates or vicinal dichloro(vinyl) phosphonates. One of the vinyl thiocyanato-phosphonates is characterized by single crystal X-ray crystallography.
Funding
We thank the Council of Scientific and Industrial Research (CSIR), Department of Science and Technology (DST-FIST and PURSE), and University Grants Commission (UGC-UPE-2) for financial support.