Pre-organized oligofunctional ligands based on rctt-C-naphthyl-resorcinarene: Synthesis and complex formation

GRAPHICAL ABSTRACT

ABSTRACT

Synthesis of pre-organized oligofunctional ligands based on ortho-methyl-tetra-C-naphthyl-resorcinarene existing in the chair conformation was carried out. By selective modification derivatives differing in the nature of functional groups immobilized on the horizontal and vertical benzene rings of resorcinarene skeleton were obtained. The abilities of the synthesized compounds to form complexes with d-, f-elements and organic amines were considered.

KEYWORDS:

• С-Naphthyl-resorcinarene
• heteromodification
• complex formation
• lanthanides
• heavy metals
• organic amines

Funding

The work was supported in part by the Russian Foundation for Basic Research (project no. 15-03-03345a).