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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 193, 2018 - Issue 12
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Short Communication

Novel cobalt nitride-induced oxygen activation on Pt-based catalyst for catalytic oxidation

Xin ChangDepartment of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P. R. China;
,
Yan ShiDepartment of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P. R. China;
,
Zhiwei YaoDepartment of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P. R. China; Correspondence[email protected] [email protected]
,
Xiaoxue KangDepartment of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P. R. China;
,
Baojiang JiangKey Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin, P. R. ChinaCorrespondence[email protected] [email protected]
&
Yue SunDepartment of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P. R. China;
Pages 848-852 | Received 22 Apr 2018, Accepted 16 Aug 2018, Published online: 08 Oct 2018
 
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Abstract

Cobalt nitride as a new type of O2 activator was used to modify Pt-based catalyst for catalytic oxidation. The nitrided Co/Pt/γ-Al2O3 catalyst system was highly efficient for preferential CO oxidation in excess H2 at low temperatures, which was attributed to a noncompetitive dual-site reaction pathway.

GRAPHICAL ABSTRACT

Acknowledgements

The work was supported by the National Natural Science Foundation of China (No. 21276253), the Liaoning Province Natural Science Foundation (No. 20180551272) and the Project of Liaoning Province Department of Education (No. L2017LZD003).

Disclosure statement

No potential conflict of interest was reported by the authors.

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