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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Luminescent complexes of 1,5-diaza-3,7-diphosphacyclooctanes with coinage metals

Andrey A. KarasikArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaCorrespondence[email protected]
,
Igor D. StrelnikArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
,
Elvira I. MusinaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
,
Irina R. DayanovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
,
Julia G. ElistratovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
,
Asiya R. MustafinaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
&
Oleg G. SinyashinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
 show all
Pages 410-414 | Received 29 Sep 2018, Accepted 17 Oct 2018, Published online: 17 Feb 2019
 
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Abstract

Cyclic aminomethylphosphines in general and 1,5-diaza-3,7-dihposphacyclooctanes in particular are widely used for the design of d10-metal complexes with catalytic or luminescent properties. 1,5-Diaza-3,7-diphosphacyclooctanes are chelating ligands towards Ni subgroup metals and chelating or bridging ligands towards copper subgroup metals. These ligands can be utilized for the design of polynuclear complexes with stimuli-responsive luminescence. Nowadays several complexes based on 1,5-diaza-3,7-diphosphacyclooctanes demonstrating stimuli-response of emission towards organic substrates or temperature are known. Some of the gold(I) complexes are able to sensitize the luminescent anionic rhenium cluster. Copper(I) complexes display rather strong luminescence with quantum yields 20-40%.

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