Abstract
Phosphorus-containing inherently chiral calix[4]arenes as well as calix[4]arenes substituted with phosphinoferrocene chiral groups at the lower rim are described. Stereoselective synthesis, structure, and catalytic properties of the chiral calixarenes are discussed.
Graphical Abstract
![](/cms/asset/f25dab60-0865-40e9-b5f6-96bfd02ab913/gpss_a_1539994_uf0001_oc.jpg)