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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

Electrochemical phosphorylation of arenes catalyzed by cobalt under oxidative and reductive conditions

S. O. StrekalovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0002-7940-7895
ORCID Icon,
V. V. GrinenkoArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaCorrespondence[email protected]
ORCID Iconhttp://orcid.org/0000-0001-9235-3089
ORCID Icon,
T. V. GryaznovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0002-8076-8540
ORCID Icon,
A. I. KononovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0002-2038-537X
ORCID Icon,
E. L. DolengovskiArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0001-5745-3738
ORCID Icon &
Y. H. BudnikovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, Russia
Pages 506-509 | Received 29 Sep 2018, Accepted 23 Oct 2018, Published online: 30 Dec 2018
 
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Abstract

Catalyst capable to operate in cathode and anode spaces simultaneously was found. Electrochemical regeneration of active form of catalyst Co2+bpy (1%) under oxidative as well as reductive conditions allows the C–H/P–H coupling of dialkyl-H-phosphonate and various aromatic or heteroaromatic compounds.

Graphical Abstract

Acknowledgements

The authors gratefully acknowledge the Russian Science Foundation No 14-23-00016 for financial support.

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