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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

Synthesis and membrane-transport properties of phosphorylated diamines, azapodands and their derivatives

Rafael A. CherkasovKazan Federal University, Kazan, Russia; ORCID Iconhttp://orcid.org/0000-0001-8604-9953View further author information
ORCID Icon,
Airat R. GarifzyanovKazan Federal University, Kazan, Russia; ORCID Iconhttp://orcid.org/0000-0002-6613-8788View further author information
ORCID Icon,
Natal’ya V. DavletshinaKazan Federal University, Kazan, Russia; Correspondence[email protected]
ORCID Iconhttp://orcid.org/0000-0003-0231-337XView further author information
ORCID Icon,
Aynaz Z. GaynullinKazan Federal University, Kazan, Russia; ORCID Iconhttp://orcid.org/0000-0002-4855-0920View further author information
ORCID Icon,
Olga N. KataevaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0002-9763-5947View further author information
ORCID Icon &
Kamil A. IvshinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Kazan, RussiaORCID Iconhttp://orcid.org/0000-0002-9720-7977View further author information
ORCID Icon
Pages 560-564 | Received 28 Sep 2018, Accepted 27 Oct 2018, Published online: 09 Jan 2019
 
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Abstract

Membrane–transport properties of synthesized phosphorylated azapodands of a series of metals of I groups were studied. The investigation of the processes of passive membrane ion transport showed the phosphorylated azapodands 2 and 3 were the most selective with respect to the lithium ion. A monophosphorylated podand, which contain a heterocyclic nitrogen atom 8-(1-diamylphosphoryl-3,5-dioxapentane) quinoline 7 was synthesized. The molecular structure of the complex of a podande 7 with a copper ion was determined by the method of X-ray analysis.

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Funding

This work funded by the subsidy allocated to Kazan Federal University for the state assignment in the sphere of scientific activities (No. 4.5888.2017/8.9).

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