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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

Novel Cu(I) complexes of functionalized phosphines

S. LinertDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany; Correspondence[email protected]
,
S. WagnerDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany;
,
P. SchmidtDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany;
,
L. HighamSchool of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, UK
,
C. HepplesSchool of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, UK
,
P. WaddellSchool of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, UK
&
K. KaraghiosoffDepartment of Chemistry, Ludwig-Maximilian University, Munich, Germany; ORCID Iconhttp://orcid.org/0000-0002-8855-730X
ORCID Icon show all
Pages 565-568 | Received 28 Sep 2018, Accepted 27 Oct 2018, Published online: 11 Dec 2018
 
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Abstract

Novel tertiary phosphines R’PR2 with additional functionalities in the substituent R have been designed and prepared according to literature procedures. The coordination behavior of the additional functionality in the organic moiety and the phosphorus atom towards different Cu(I) salts was investigated. These reactions resulted in polynuclear complexes with unexpected structures involving Cu(I) atoms with different coordination numbers in the same compound.

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