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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 4-6: Proceedings of the 2018 International Conference on Phosphorus Chemistry, ICPC-22
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Original Articles

The unusual reaction of alkylation of dicarboxylate phosphabetaines in alcohol media

Yuliya V. BakhtiyarovaKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; Correspondence[email protected]
ORCID Iconhttp://orcid.org/0000-0002-1865-274XView further author information
ORCID Icon,
Maxim V. MorozovKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
,
Rail R. MinnullinKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
,
Kamil A. IvshinKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
,
Luiza N. YamalievaKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
,
Irina V. GalkinaKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
,
Olga N. KataevaKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; ;A. E. Arbuzov Institute of Organic and Physical Chemistry, Laboratory of Diffraction Research Methods, Kazan, RussiaView further author information
&
Vladimir I. GalkinKazan Federal University, Alexander Butlerov Institute of Chemistry, Kazan, Russia; View further author information
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Pages 580-584 | Received 30 Sep 2018, Accepted 09 Nov 2018, Published online: 09 Jan 2019
 
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Abstract

The new reaction of alkylation of dicarboxylate phosphabetaines by alkyl halides in alcohol media has been opened. In this reaction alkyl radical enters to the ester part of molecule not from alkyl halide, but from the alcohol molecule. The structure of the isolated compounds was determined by IR and NMR spectroscopy, elemental and X-ray analysis.

Graphical Abstract

Funding

This work was funded by the subsidy allocated to Kazan Federal University for the state assignment in the sphere of scientific activities (no. 4.5888.2017/8.9).

Table 1. Characteristics of quaternary phosphonium salts 11a–e.

Figure 1. Molecular structure of compounds 11b and 11c.

Figure 1. Molecular structure of compounds 11b and 11c.

Additional information

Funding

This work was funded by the subsidy allocated to Kazan Federal University for the state assignment in the sphere of scientific activities (no. 4.5888.2017/8.9)

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