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Abstract
A combination of CuI with oxalic diamide is a powerful catalytic system for cross-coupling reaction of thiols with aryl bromides and chlorides. It is important to note that unactivated aryl chorides are coupled smoothly with aryl- and alkyl thiols to give the corresponding thioethers in good to excellent yields for the first time.
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Funding
This work was financially supported by the Ministry of Science and Technology, Taiwan (MOST 107-2113-M-005-019-MY3); National Chung Hsing University; Research Center for Sustainable Energy and Nanotechnology (NCHU) and the “Innovation and Development Center of Sustainable Agriculture” from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education (MOE) in Taiwan.