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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 194, 2019 - Issue 10: Proceedings of the 2018 International Conference on Phosphorus, Boron and Silicon, PBSi 2018
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Original Articles

Novel sterically hindered ferrocenyl-phosphonium salt

Liliya KadyrgulovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian FederationView further author information
,
Vadim ErmolaevArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian FederationCorrespondence[email protected]
View further author information
,
Leysan GilmanovaArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian FederationView further author information
&
Vasiliy MiluykovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russian FederationView further author information
Pages 989-991 | Received 20 May 2019, Accepted 07 Jun 2019, Published online: 17 Jun 2019
 
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Abstract

New sterically hindered ferrocenyl containing phosphonium salt was synthesized in two steps starting from ferrocene. To avoid halogen contamination di-tert-butylferrocenylphosphine was quaternized with methyl bis(trifluoromethanesulfonyl)imide directly. Obtained phosphonium salt was characterized with several physical methods.

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Additional information

Funding

T
he authors are grateful to the Assigned Spectral-Analytical Center of FRC Kazan Scientific Center of RAS for technical assistance in research.

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