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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 196, 2021 - Issue 4
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Review

Synthesis of α-aminophosphonates by the Kabachnik-Fields reaction

G. Sravyaa Chemical Engineering Institute, Ural Federal University, Yekaterinburg, Russian Federation
,
A. Balakrishnab Rajeev Gandhi Memorial College of Engineering and Technology (Autonomous), Nandyal, Andhra Pradesh, India
,
Grigory V. Zyryanova Chemical Engineering Institute, Ural Federal University, Yekaterinburg, Russian Federation;c I. Ya. Postovskiy Institute of Organic Synthesis, Ural Division of the Russian Academy of Sciences, Yekaterinburg, Russian FederationCorrespondence[email protected] [email protected]
,
G. Mohand Department of Chemistry, Sri Venkateswara University, Tirupati, Andhra Pradesh, India;e DST-PURSE Centre, Sri Venkateswara University, Tirupati, Andhra Pradesh, India
,
C. Suresh Reddyd Department of Chemistry, Sri Venkateswara University, Tirupati, Andhra Pradesh, India
&
N. Bakthavatchala Reddya Chemical Engineering Institute, Ural Federal University, Yekaterinburg, Russian FederationCorrespondence[email protected] [email protected]
Pages 353-381 | Received 28 Sep 2020, Accepted 09 Nov 2020, Published online: 14 Dec 2020
 
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Abstract

The review discusses recent achievements in the development of more ecofriendly and economically viable processes for the synthesis of biologically potent α-aminophosphonates via Kabachnik-Fields reaction by three-component coupling of carbonyl, amine and hydrophosphoryl compounds. These α-aminophosphonates exhibited promising antioxidant, antimicrobial and anticancer activity. Some recent developments on the synthesis of biologically active α-aminophosphonates in the presence of various catalysts, in catalytic solvent medium, in catalyst-free solvent medium, under solvent-free conditions, and reactions in solution are discussed. Miscellaneous reactions are also included.

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