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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 196, 2021 - Issue 10
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Short Communication

Copper-catalyzed three-component ortho-selective selenation of phenols

Run Luoa School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou, P.R. ChinaView further author information
,
Lina Guoa School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou, P.R. ChinaView further author information
,
Meiyun Sua School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou, P.R. ChinaView further author information
,
Wenjie Liua School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou, P.R. China;b Guangdong Cosmetics Engineering and Technology Research Center, Guangzhou, P.R. ChinaCorrespondence[email protected]; [email protected]
View further author information
&
Shaohua Wanga School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Guangzhou, P.R. China;b Guangdong Cosmetics Engineering and Technology Research Center, Guangzhou, P.R. ChinaCorrespondence[email protected]; [email protected]
View further author information
Pages 896-901 | Received 16 Feb 2021, Accepted 16 Jun 2021, Published online: 09 Jul 2021
 
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Abstract

An efficient and convenient copper-catalyzed three-component reaction has been developed for the arylselenation of phenols with Se powder and aryl iodides. This one-pot procedure provides a straightforward approach to the synthesis of ortho-arylselenylphenols with high regioselectivity. This practical process shows good functional group tolerance, providing the corresponding products in moderate to good yields.

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Additional information

Funding

The work was financially supported by the Foundation for Natural Science Foundation of Guangdong Province (2017A030313297) and special funds of key disciplines from Guangdong and Zhongshan cooperation.

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