Advanced search
Publication Cover
Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
Submit an article Journal homepage
289
Views
0
CrossRef citations to date
0
Altmetric
Articles

Hydrolysis and alcoholysis of phosphinates and phosphonates

Nikoletta HarságiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0003-1511-0889View further author information
ORCID Icon,
Betti SzőllősiDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryView further author information
,
Petra Regina VargaDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryORCID Iconhttps://orcid.org/0000-0001-9870-6420View further author information
ORCID Icon &
György KeglevichDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, HungaryORCID Iconhttps://orcid.org/0000-0002-5366-472XView further author information
ORCID Icon
Pages 523-525 | Received 01 Oct 2021, Accepted 06 Oct 2021, Published online: 26 Oct 2021
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

Phosphinic and phosphonic acids useful intermediates and biologically active compounds may be prepared from their esters: phosphinates and phosphonates, respectively, by acid-catalyzed hydrolysis either on conventional heating or on MW irradiation. The transesterification of alkyl phosphinates took place only in the presence of suitable ionic liquids as the catalysts. In the cases of phenylphosphonates, depending on the nature of the ionic liquid, the formation of the ester was accompanied by the fission of the C–O bond.

Graphical Abstract

Additional information

Funding

This project was supported by the National Research, Development and Innovation Office (K134318). N.H. is grateful for the ÚNKP-21-3-II-BME-294 New National Excellence Program of the Ministry of Human Capacities.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 2,235.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.