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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Articles

A double phosphabetaine formed from 1,3,5-triaza-7-phosphaadamantane (PTA) with acetylenedicarboxylic acid and its Ag(CF3SO3)-based coordination polymer

Csenge Tamara Szolnokia Department of Physical Chemistry, University of Debrecen, Debrecen, Hungary;b Doctoral School of Chemistry, University of Debrecen, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0001-9280-6869View further author information
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Gyula Tamás Gála Department of Physical Chemistry, University of Debrecen, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0002-0021-3693View further author information
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Éva Kovátsc Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Budapest, HungaryORCID Iconhttps://orcid.org/0000-0002-8358-857XView further author information
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Gábor Pappa Department of Physical Chemistry, University of Debrecen, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0001-5939-8525View further author information
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Henrietta Horváthd MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0002-9046-1665View further author information
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Ferenc Joóa Department of Physical Chemistry, University of Debrecen, Debrecen, Hungary;d MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0001-9457-8038View further author information
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Ágnes Kathóa Department of Physical Chemistry, University of Debrecen, Debrecen, HungaryORCID Iconhttps://orcid.org/0000-0003-4853-6114View further author information
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Antal Udvardya Department of Physical Chemistry, University of Debrecen, Debrecen, HungaryCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-6320-8322View further author information
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Pages 561-563 | Received 25 Oct 2021, Accepted 10 Nov 2021, Published online: 29 Nov 2021
 
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Abstract

The adduct of acetylenedicarboxylic acid and the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA, 1) in 1:2 molar ratio, was synthesized both in aqueous solution and under anhydrous conditions in a planetary ball mill (pbm). The resulting double phosphabetaine (2) was characterized by 1H-, 13C-, and 31P-NMR spectroscopy, ESI-mass spectroscopy, and elemental analysis, furthermore, its solid-state structure was determined by single crystal X-ray diffraction. SXRD also revealed that in aqueous solution 2 reacted with AgSO3CF3 to yield a 2 D polymer.

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Funding

The financial support of the Hungarian National Research, Development and Innovation Office (FK-128333) is greatly acknowledged. Project no. TKP2020-NKA-04 has been implemented with the support provided from the National Research, Development and Innovation Fund of Hungary, financed under the 2020-4.1.1-TKP2020 funding scheme. The research was supported by the EU and co-financed by the European Regional Development Fund under the projects GINOP-2.3.3-15-2016-00004 and GINOP 2.3.2-15-2016-00008.

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