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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Review

Phosphonodithioformate-amine coupling reaction: from basic discovery to application for the functionalization of liposomes

Montassar Khalila Univ Brest, CNRS, CEMCA MR 6521, Brest, France
,
Dany Jeanne Dit Fouquea Univ Brest, CNRS, CEMCA MR 6521, Brest, France
,
Mathieu Berchela Univ Brest, CNRS, CEMCA MR 6521, Brest, France
,
Aurore Fraixb PhotoChemLab, Department of Drug and Health Sciences, University of Catania, Catania, Italy
,
Salvatore Sortinob PhotoChemLab, Department of Drug and Health Sciences, University of Catania, Catania, Italy
,
Antony Memboeufa Univ Brest, CNRS, CEMCA MR 6521, Brest, France
&
Paul-Alain Jaffrèsa Univ Brest, CNRS, CEMCA MR 6521, Brest, FranceCorrespondence[email protected]
 show all
Pages 462-467 | Received 30 Sep 2021, Accepted 25 Nov 2021, Published online: 14 Dec 2021
 
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Abstract

This short review article is dedicated to the Phosphonodithioformate-Amine Coupling (PAC) reaction. This reaction occurs by mixing phosphonodithioformate with amine without any catalyst and produces, according to a fast second order kinetics, phosphonothioamide. This reaction was applied to the functionalization of liposomes and opens new possibilities for the functionalization of synthetic or biologic materials.

Graphical Abstract

Acknowledgements

We thank IBSAM, CNRS and the University of Brest (UBO).

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