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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 5-6: ICPC-23: 23rd International Conference on Phosphorus Chemistry; Guest Editors:Professor Jozef Drabowicz; Professor Piotr Kiełbasiński and Professor Tomasz Cierpiał
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Articles

Convenient preparative approaches to biorelevant dimethylphosphinoyl-derived compounds with the use of (trimethylsilyl)dimethylphosphinite

Anastasiia M. Aleksandrovaa Institute of Organic Chemistry, National Academy of Sciences, Kyiv, Ukraine
,
Ludmyla V. Bezgubenkoa Institute of Organic Chemistry, National Academy of Sciences, Kyiv, Ukraine
,
Alona S. Cherednichenkoa Institute of Organic Chemistry, National Academy of Sciences, Kyiv, Ukraine
,
Petro P. Onys’koa Institute of Organic Chemistry, National Academy of Sciences, Kyiv, Ukraine
&
Yuliya V. Rassukanaa Institute of Organic Chemistry, National Academy of Sciences, Kyiv, Ukraine;b National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, UkraineCorrespondence[email protected]
Pages 571-573 | Received 28 Oct 2021, Accepted 29 Dec 2021, Published online: 20 Jan 2022
 
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Abstract

A convenient procedure for the preparation of (trimethylsilyl)dimethylphosphinite was developed. The synthetic potential of the latter was exemplified by the preparation of dimethylphosphinoyl-derived nitriles, amines, acetone, acetic and acetoacetic acids as valuable building blocks for medicinal and materials chemistry.

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