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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 197, 2022 - Issue 11
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Research Articles

1,3,4,6-Tetrachloroglycoluril (TCGV) mediated isothiocyanation of phosphites, phosphonites and phosphinites

Huichuang GuoState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. ChinaORCID Iconhttps://orcid.org/0000-0003-1715-5095
ORCID Icon,
Junchen LiState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China
,
Yulong ZhangState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China
,
Tengfei MaoState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China
,
Runli GaoState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China
,
Yongbiao GuoState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. China
&
Enxue ShiState Key Laboratory of NBC Protection, State Key Laboratory of NBC Protection for Civilian, Beijing, P.R. ChinaCorrespondence[email protected] [email protected]
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Pages 1157-1159 | Received 21 Feb 2022, Accepted 05 Apr 2022, Published online: 19 Apr 2022
 
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Abstract

A universal and facile isothiocyanation protocol of  P(O)H functionality with inorganic thiocyanides mediated by 30% equimolar 1,3,4,6-tetrachloroglycoluril (TCGV) was developed for the preparation of the corresponding phosphoroisothiocyanates, phosphonoisothiocyanates and phosphinoisothiocyanates. P(O)Cl was found to be the intermediate in situ formed in the reaction.

Graphical Abstract

Conflict of interest

The authors declare no conflict of interest.

Notes

1 H. Guo, J. Li, Y. Zhang, T. Mao, R. Gao, Y. Guo, E. Shi

State Key Laboratory of NBC Protection for Civilian,

Beijing 102205, P. R. China

E-mail: [email protected]

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