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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 53, 1990 - Issue 1-4
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Original Articles

PHOSPHORUS-NITROGEN COMPOUNDS. PART 64.1 THE REACTIONS OF HEXACHLOROCYCLOTRIPHOSPHAZATRIENE WITH 2, 2-DIMETHYLPROPANE-1, 3-DIOL. NUCLEAR MAGNETIC RESONANCE STUDIES OF THE PRODUCTS

Homaid A. Al-Madfa Department of Chemistry, Birkbeck College (University of London), Gordon House, 29 Gordon Square, London, WC1H OPP, U.K.
,
Robert A. Shaw Department of Chemistry, Birkbeck College (University of London), Gordon House, 29 Gordon Square, London, WC1H OPP, U.K.
&
Sidit Ture Department of Chemistry, Birkbeck College (University of London), Gordon House, 29 Gordon Square, London, WC1H OPP, U.K.
Pages 333-338 | Received 05 Dec 1989, Accepted 01 Feb 1990, Published online: 23 Sep 2006
 
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Abstract

The reactions of hexachlorocyclotriphosphazatriene, N3 P3 CI6, with 2, 2-dimethylpropane-1, 3-diol yield monospiro-, N3 P3 Cl4 [(OCH2)2 CMe2, dispiro-, N3 P3 Cl4((OCH2)2CMe2|2, and trispiroderivatives, N3 P3 ((OCH2)2, CMe2]3. An ansa, N3 P3 CI4 [(OCH2)2 CMe2]2 and a spiro-ansa, N3 P3 Cl2- ((OCH2), CMe2,]2 and a doubly-bridged compound, (N3 P3 Cl4,)2[(OCH2)]2 were also isolated. Product types and relative yields were compared with those arising from propane-1, 3-diol. The yields of ansa products from the reactions of the dimethyl diol seem to be considerably enhanced relative to those of its unmethylated analogue. 31P and 1H n.m.r. spectra are reported.

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Related Research Data

The reactions of non-gem-hexanedioxytetrachlorocyclotriphosphazene with 2-(2-hydroxyethyl)thiophene, benzyl alcohol and 1,1,3,3-tetramethylguanidine. Spectroscopic studies of the derived products
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