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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 53, 1990 - Issue 1-4
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Communication

Pt(II) ASSISTED DEOXYGENATION OF COORDINATED SULFOXIDES BY HYDROCHLORIC- OR HYDROBROMIC ACID

Vadim Yu. Kukushkin Chemical Department, Leningrad State University, Universitetsky pr., 2, 198904, Stary, Petergof, USSR
,
Elena A. Aleksandrova Chair of General and Inorganic Chemistry, Lensovet Technological Institute, Zagorodny pr., 49, 198013, Leningrad, USSR
&
Boris V. Zhadanov NPO IREA, Bogorodsky Val, 3, 107258, Moscow, USSR
Pages 433-435 | Received 30 Jan 1990, Published online: 23 Sep 2006
 
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Abstract

The interaction of the complexes (Et4 N)[Pt(R2 SO)X3] (R = Me, Et, CH2 Ph, X [dbnd] C1; R [dbnd] Me, X [dbnd] Br) and cis-[Pt(Me2 SO)2 Cl2] with concentrated HX (X [dbnd] Cl. Br) results in the reduction of the coordinated sulfoxides and oxidation of Pt(II) to Pt(IV). As a result [Pt(R2 S)X5 and [Pt(R2S)2 X4] are formed. Ligands R2 S can be removed from the complexes and isolated in a free state.

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