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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 49-50, 1990 - Issue 1-4
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Section 1: Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

Nucleophilic Displacement Reactions on Phosphoric Esters and Amides by Lithium Reagents. A Powerful Tool in Organic Synthesis

Philippe Savignac Laboratoire DCPH, Ecole Polytechnique, 91128, Palaiseau cedex, France
,
Marie-Paule Teulade Laboratoire DCPH, Ecole Polytechnique, 91128, Palaiseau cedex, France
&
Carl Patois Laboratoire DCPH, Ecole Polytechnique, 91128, Palaiseau cedex, France
Pages 169-172 | Published online: 04 Oct 2006
 
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Abstract

Alkylation of phoshoric esters and amides by lithium reagents represents a new rouge to α-lithioalkylphosphonates. converssion of which leads to phosphoryl stabilized anions of synthetic use.

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