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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 51, 1990 - Issue 1-4
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Poster Program: Section 1 Synthesis, Structure, Stereochemistry and Reactivity of Organophosphorus Compounds

The Structure and Spectroscopy of α-Hydroxyphosphonates

H. R. Hudson Department of Applied Chemistry and Life Sciences, The Polytechnic of North London, Holloway Road, London, N7 8DB, U.K.
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R. W. Matthews Department of Applied Chemistry and Life Sciences, The Polytechnic of North London, Holloway Road, London, N7 8DB, U.K.
,
M. McPartlin Department of Applied Chemistry and Life Sciences, The Polytechnic of North London, Holloway Road, London, N7 8DB, U.K.
,
H. Powell Department of Applied Chemistry and Life Sciences, The Polytechnic of North London, Holloway Road, London, N7 8DB, U.K.
,
R. O. Yusuf Department of Applied Chemistry and Life Sciences, The Polytechnic of North London, Holloway Road, London, N7 8DB, U.K.
,
Zs. M. Jászay Department of Organic Chemical Technology, Technical University of Budapest, H-1521, Budapest, HUNGARY
,
Gy. Keglevich Department of Organic Chemical Technology, Technical University of Budapest, H-1521, Budapest, HUNGARY
,
I. Petneházy Department of Organic Chemical Technology, Technical University of Budapest, H-1521, Budapest, HUNGARY
&
L. Tóke Department of Organic Chemical Technology, Technical University of Budapest, H-1521, Budapest, HUNGARY
 show all
Page 230 | Published online: 26 May 2009
 
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Abstract

α-Hydroxyphosphonates are important intermediates in the preparation of various organophosphorus compounds. Methods for their preparation have been described.1 We now report new aspects of their structure and spectroscopy. In the solid state, O,O-dimethyl α-hydroxy-α-phenyl-β-chloroethylphosphonate has been shown by X-ray diffraction studies to consist of hydrogen-bonded dimers with a hydrosen-bond length between the phosphoryl oxygen and hydroxyl hydrogen atom of 1.74 Å. The P=0 bond is relatively short (1.463).

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