PHOSPHORUS-NITROGEN COMPOUNDS. PART 66.¹ THE REACTIONS OF OCTACHLOROCYCLOTETRA-PHOSPHAZATETRAENE WITH 2,2-DIMETHYLPROPANE-1,3-DIOL. SYNTHETIC AND NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC INVESTIGATIONS

Homaid A. Al-madfa Department of Chemistry, Birkbeck College (Universiry of London), Gordon House, 29, Gordon Square, London, WCIH OPP, UK

Robert A. Shawt Department of Chemistry, Birkbeck College (Universiry of London), Gordon House, 29, Gordon Square, London, WCIH OPP, UK

Abstract

The reactions of octachlorocyclotetraphosphazatetraene. N₄P₄Cl₈, with 2,2-dimethylpropane-1,3-diol gave the following isolated and characterised derivatives; N₄P₄Cl₆[(OCH₂)₂CMe ₂], N₄P₄Cl₂[(OCH₂)₂CMe ₂]₂ (2 isomers) and N₄P₄CI₂[(OCH₂)₂CMe₂]₃. ³¹P. ¹H and ¹³C n.m.r. spectroscopic investigations showed all derivatives to have spiro structures. The isomeric bis derivatives have 2,2.4,4- and 2,2.6,6-structures.

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PHOSPHORUS-NITROGEN COMPOUNDS. PART 66.¹ THE REACTIONS OF OCTACHLOROCYCLOTETRA-PHOSPHAZATETRAENE WITH 2,2-DIMETHYLPROPANE-1,3-DIOL. SYNTHETIC AND NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC INVESTIGATIONS

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PHOSPHORUS-NITROGEN COMPOUNDS. PART 66.1 THE REACTIONS OF OCTACHLOROCYCLOTETRA-PHOSPHAZATETRAENE WITH 2,2-DIMETHYLPROPANE-1,3-DIOL. SYNTHETIC AND NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC INVESTIGATIONS

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PHOSPHORUS-NITROGEN COMPOUNDS. PART 66.¹ THE REACTIONS OF OCTACHLOROCYCLOTETRA-PHOSPHAZATETRAENE WITH 2,2-DIMETHYLPROPANE-1,3-DIOL. SYNTHETIC AND NUCLEAR MAGNETIC RESONANCE SPECTROSCOPIC INVESTIGATIONS