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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 66, 1992 - Issue 1-4
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Original Articles

SYNTHESE DE NOUVEAUX DERIVES DU THIOPHENE

Boualem Oussaid U.R.A. au C.N.R.S. n° 454, Laboratoire de Synthèse, Structure et Réactivité de Molécules Phosphorées, 118 Route de Narbonne, 31062, Toulouse Cedex, France
,
Leïla Najem U.R.A. au C.N.R.S. n° 454, Laboratoire de Synthèse, Structure et Réactivité de Molécules Phosphorées, 118 Route de Narbonne, 31062, Toulouse Cedex, France
&
Bernard Garrigues U.R.A. au C.N.R.S. n° 454, Laboratoire de Synthèse, Structure et Réactivité de Molécules Phosphorées, 118 Route de Narbonne, 31062, Toulouse Cedex, France
Pages 13-20 | Received 15 Oct 1991, Accepted 28 Oct 1991, Published online: 23 Sep 2006
 
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Abstract

New potentially active drugs derivatives of 2,5-disubstituted thiophene are synthesized by a multistep procedure. An alcohol solution of ammonia reacts with 2-formyl thiophene to form the gem-diimine 8. The oxide of benzonitrile reacts with 2-[(methylimino)methyl] or 3-[(methylimino)methyl] thiophene to form the corresponding-1,2,4 oxadiazolines (9 and 10).

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