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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 97, 1994 - Issue 1-4
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Original Articles

INFLUENCE OF IODINE ON THE REACTIVITY OF TETRAPHOSPHORUS TRISULFIDE IN ORGANIC REACTIONS

Il'yas S. Nizamov A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420083, Kazan, Russia
,
Gyuzel' G. Garifzyanova A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420083, Kazan, Russia
,
Lyubov' A. Al'metkina A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420083, Kazan, Russia
,
Gul'nur G. Sergeenko A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420083, Kazan, Russia
&
Elvira S. Batyeva A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420083, Kazan, Russia
Pages 173-182 | Received 16 Aug 1994, Published online: 24 Sep 2006
 
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Abstract

The reactivity of β-tetraphosphorus trisulfide is increased through involvement of elemental iodine in the reactions with dialkyl disulfides, thioacetals and animals. The reactions of β-and α-diiodotetra-phosphorus trisulfides with disulfides, thioacetals and aminals were studied. The proposed reaction mechanism is discussed.

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