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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 92, 1994 - Issue 1-4
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Original Articles

Selective Oxidation of Sulfides to Sulfoxides by Atmospheric Oxygen and Aldehyde Catalysed by NIII Complexes

Stephane Vincent Université Denis Diderot Paris VII, associé au CNRS URA 34 1, rue Guy de la Brosse, 75005, Paris, France
,
Claude Lion Université Denis Diderot Paris VII, associé au CNRS URA 34 1, rue Guy de la Brosse, 75005, Paris, France
,
Mir Hedayatullah Université Denis Diderot Paris VII, associé au CNRS URA 34 1, rue Guy de la Brosse, 75005, Paris, France
,
Anthony Challier Université Denis Diderot Paris VII, associé au CNRS URA 34 1, rue Guy de la Brosse, 75005, Paris, France
,
Gerard Delmas Ministère de la Défense Nationale, Centre d'Etudes du Bouchet, B.P. 3 91710, Vert-Le-Petit, France
&
Gilbert Magnaud Ministère de la Défense Nationale, Centre d'Etudes du Bouchet, B.P. 3 91710, Vert-Le-Petit, France
Pages 189-192 | Received 21 Jun 1994, Published online: 24 Sep 2006
 
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Abstract

A new and efficient method for oxidising sulfides selectively to sulfoxides has been developed with atmospheric oxygen, in the presence of isobutyraldehyde and catalysed by NiII complexes such as bis[1,3-bis-(p-methoxyphenyl)-1,3-propanedionato]nickel, [Ni(dmp)2], and bis[acetylacetonato]nickel, [Ni(acac)2].

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