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Original Articles

OXYDES DE N-2-ACYL DIAZAPHOSPHOLINES-1,2,3: SYNTHESE, REACTIVITE ET ETUDE SPECTROGRAPHIQUE IR ET DE RMN 1H, 31P, 13C

, , , , &
Pages 1-7 | Received 11 Jan 1994, Accepted 30 Dec 1994, Published online: 04 Oct 2006
 

Abstract

The monoacylhydrazides, as well as hydrazines, react with phosphoallenic derivatives 1 to lead to the δ5-N-2 acyl 3-dimethylamino 3-oxo-1,2,3-diazaphospholine 2 . The reaction of ring opening in δ5-N-2 acyl-3-dimethylamino-3-oxo-1,2,3-diazaphospholine by different alcohols leads to the β-phosphonyl-hydrazide 3 . The structure of products ( 2 and 3 ) is further confirmed by IR, 1H, NMR, 13P NMR, 13C NMR spectra.

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