SYNTHESIS OF 1-AMINOALKANEPHOSPHONIC ACID DERIVATIVES CONTAINING FURAN MOIETY. PART II: FIRST SYNTHESIS OF (2-FURYL)AMINOMETHANE PHOSPHONIC ACID¹

Louis Cottier Université Lyon I, Laboratoire de Chimie Organique, URA CNRS 463, 43 Bd du 11 Novembre 1918, 69622, Villeurbanne Cedex, FRANCE

GÉRard Descotes Université Lyon I, Laboratoire de Chimie Organique, URA CNRS 463, 43 Bd du 11 Novembre 1918, 69622, Villeurbanne Cedex, FRANCE

Grzegorz Gonera University of Łódź, Department of Organic Chemistry, Narutowicza 68, 90-136, Łódź, POLAND

Grzegorz Grabowski University of Łódź, Department of Organic Chemistry, Narutowicza 68, 90-136, Łódź, POLAND

Jaroslaw Lewkowski University of Łódź, Department of Organic Chemistry, Narutowicza 68, 90-136, Łódź, POLAND

Romuald Skowroński University of Łódź, Department of Organic Chemistry, Narutowicza 68, 90-136, Łódź, POLAND

Abstract

The synthesis of (2-furyl)aminomethanephosphonic acid from furfural via corresponding imine, dibenzyl ester and N-benzylsubstituted acid is presented. The synthesis was performed by the hydrogenolysis of a corresponding N-benzylsubstituted dibenzyl ester.

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SYNTHESIS OF 1-AMINOALKANEPHOSPHONIC ACID DERIVATIVES CONTAINING FURAN MOIETY. PART II: FIRST SYNTHESIS OF (2-FURYL)AMINOMETHANE PHOSPHONIC ACID¹

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SYNTHESIS OF 1-AMINOALKANEPHOSPHONIC ACID DERIVATIVES CONTAINING FURAN MOIETY. PART II: FIRST SYNTHESIS OF (2-FURYL)AMINOMETHANE PHOSPHONIC ACID1

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SYNTHESIS OF 1-AMINOALKANEPHOSPHONIC ACID DERIVATIVES CONTAINING FURAN MOIETY. PART II: FIRST SYNTHESIS OF (2-FURYL)AMINOMETHANE PHOSPHONIC ACID¹