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Phosphorus, Sulfur, and Silicon and the Related Elements Volume 123, 1997 - Issue 1
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Original Articles

DESULFURISATION OF PHOSPHONYLATED THIOAMIDES: A NEW WAY TO FUNCTIONALISED AMINOPHOSPHONATES

Sylve Le Roy-gourvennec Laboratoire de Chimie Moléculaire et Thio-organique (URA CNRS 480), ISMRA-Université de Caen, F-14050, Caen, France
,
Margareth Lemarie Laboratoire de Chimie Moléculaire et Thio-organique (URA CNRS 480), ISMRA-Université de Caen, F-14050, Caen, France
&
Serge Masson Laboratoire de Chimie Moléculaire et Thio-organique (URA CNRS 480), ISMRA-Université de Caen, F-14050, Caen, France
Pages 247-254 | Received 02 Jan 1997, Published online: 04 Oct 2006
 
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Abstract

A new way to functionalised (aminomethyl)- or (aminoethyl)-phosphonates via the desulfurisation by nickel boride of phosphono substituted thioamides [(thiocarbamoyl)- and (thiocarbamoylmethyl)-hosphonates], readily available from phosphono-dithioesters and functionalised amines, is described.

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