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Original Articles

ELEMENTAL SELENIUM REACTIONS WITH 4-ETHYLPYRIDINE

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Pages 13-28 | Received 23 Dec 1997, Accepted 18 Feb 1998, Published online: 24 Sep 2006
 

Abstract

A reaction of elemental selenium with 4-ethylpyridine has been studied. The process was run in sealed ampuls, within 205–240 & deg;C, under nitrogen. The reaction products were indentified by GC-MS and 1H NMR. The following products have been identified: (4-pyridyl)hydroxymethyl ketone, (4-pyridyl)methyl ketone, (4-pyridyl)-hydroselenomethyl ketone. 2,3-di(4-pyridyl)butane, 1,3-di(4-pyridyl)butane, 1-(4-pyridyl)-1-[2-(4-ethyl)pyridyl]-ethane, 1-(4-pyridyl)-1-[2-(4-ethenyl)pyridyl]ethane.

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