SYNTHESIS AND X-RAY STRUCTURE OF 6-CYANO-2,10-DIOXA-1-PHOSPHABICYCLO [4.4.0]DECANE-1-OXIDE

Natalya M. Vinogradova A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Konstantin A. Lyssenko A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Irene L. Odinets A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Pavel V. Petrovskii A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Tatyana A. Mastryukova A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Martin I. Kabachnik A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova str., 28, 117813, Moscow, Russian Federation

Abstract

Bis(ω-chloropropyl)dialkoxyphosphonylacetonitriles 4 were established to undergo intramolecular bisdealkylation during distillation affording 6-cyano-2,10-dioxa-1-phosphabicyclo[4.4.0]decane-1-oxide 5 in high yield. The molecular structure of 5 was determined by the single crystal X-ray diffraction method. The molecule consists of cis-fused six-membered rings both in chair conformation.

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SYNTHESIS AND X-RAY STRUCTURE OF 6-CYANO-2,10-DIOXA-1-PHOSPHABICYCLO [4.4.0]DECANE-1-OXIDE

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SYNTHESIS AND X-RAY STRUCTURE OF 6-CYANO-2,10-DIOXA-1-PHOSPHABICYCLO [4.4.0]DECANE-1-OXIDE

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