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Integrated Ferroelectrics
An International Journal
Volume 145, 2013 - Issue 1
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Original Articles

Self-Assembly of Cyanostilben-Based Intramolecular Charge-Transfer Compounds

Mi Ouyang State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
,
Zhiyan Fu State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
,
Xiaojing Lv State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
,
Bin Hu State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
,
Pingjing Wang State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
&
Cheng Zhang State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, P. R., China
Pages 146-150 | Received 25 Jun 2012, Accepted 01 Feb 2013, Published online: 12 Jul 2013
 
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Abstract

A handful of cyano-stilbene derivatives are successfully synthesized through Williamson and Suzuki reaction. The dipole-dipole interaction of intramolecular charge-transfer molecule is used to self-assembly microstructure of the as-prepared materials. The CNS-1 microstructures are large-scale spherical particles. However, compound CNS-2 forms straight one-dimensional (1-D) microribbons. Additionally, the morphology of micro-structures obtained from compounds CNS-3 and CNS-5 are large-scale spheres with several micrometres.

Acknowledgments

The authors gratefully thank the supporting of National Basic Research Program of China (2010CB635108, 2011CBA00700), International S&T Cooperation Program, China (2012DFA51210) and Major Science and Technology, Special and Priority Themes of Zhejiang Province, China (2009C14004).

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