Abstract
The transparent glasses of CaO-MgO-Al2O3-SiO2-ZnO system doped with Sm2O3 was prepared by conventional melt-quenching method. The obtained glasses were heat treated at a suitable temperature (875 °C–920 °C for 2 h) identified by differential thermal analysis (DTA). Phase formation and microstructure of glass-ceramics were characterized by X-ray diffraction and scanning electron microscopy, respectively. The optical transmission spectra were recorded by UV-Vis spectrophotometer in the wavelength range between 350 and 1000 nm. It was found that the increase in heat treatment temperature reduced the transparency of the glass-ceramics. The luminescence properties were identified by fluorescence spectroscopy. The excitation spectra of Sm2O3 doped CaO-MgO-Al2O3-SiO2-ZnO glass-ceramic samples are in wavelength range of 550–750 nm and the emission spectra exhibited a strong orange-red luminescence composed of 562, 599 and 654 nm under excited at 402 nm. The results of XRD studies revealed the occurrence of diopside (CaMgSi2O6) and akermanite (Ca2MgSi2O7) phases. The increasing of heat treatment temperature has no effect on the shift of emission spectra.
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Acknowledgement
W. Senanon would like to thank the Science Achievement Scholarship of Thailand (SAST). We would also like to thank the Thailand Research Fund (BRG5780015 and IRG5780013) for financial support.