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Integrated Ferroelectrics
An International Journal
Volume 202, 2019 - Issue 1: Proceedings of the International Conference on Nano-Structured Materials and Devices (ICNSMD-2018): Part I of IV
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Section B: Dielectric Properties

Hydrogen Bonding Interaction between Amide and Alcohols: Dielectric Relaxation and FTIR Study

F. A. SaifMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India
,
P. B. UndreMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, IndiaCorrespondence[email protected]
,
S. A. YaseenMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India
,
A. S. AlameenMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India
,
S. S. PatilMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India
&
P. W. KhiradeMicrowave Research Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, India
Pages 79-88 | Received 01 Oct 2018, Accepted 12 Aug 2019, Published online: 30 Dec 2019
 
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Abstract

The dielectric relaxation study for the hydrogen bonded binary system of polar liquid N,N-dimethylacetamide in butanol and pentanol, has been carried out at 11 concentrations over the frequency range of 10 MHz–20 GHz at 303 K using TDR. The least squares fit method has been used to obtain the static dielectric constant (ε0) and relaxation time (τ). By using dielectric parameters the excess permittivity (εE), excess inverses relaxation time (1/τ)E, Kirkwood Correlation factor (g) are also obtained to explore the hydrogen-bonded hetero-molecular interactions. Conformational analysis of the hydrogen bond between the two systems is supported by the FTIR spectra.

Acknowledgments

UGC-SAP thankfully acknowledged.

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