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Integrated Ferroelectrics
An International Journal
Volume 236, 2023 - Issue 1
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Research Article

MnCoOx@Graphene Derived from Dual MOFs as Superior Anode for Lithium Ion Batteries

Shangrong Tana Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaView further author information
,
Zhuo Yaoa Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-1114-5075View further author information
ORCID Icon,
Hong Huangb Department of Mechanical and Materials Engineering, Wright State University, Dayton, Ohio, USACorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0003-4997-1089View further author information
ORCID Icon,
Zechen Liua Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaView further author information
,
Dianli Qua Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaView further author information
,
Ziqiang Lva Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaView further author information
&
Zhaoyi Huoa Collage of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan, Liaoning, P. R. ChinaORCID Iconhttps://orcid.org/0000-0001-7325-6451View further author information
ORCID Icon show all
Pages 85-95 | Received 29 Sep 2022, Accepted 09 Mar 2023, Published online: 12 Jun 2023
 
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Abstract

The MnCoOx@RGO derived from dual metal organic framework (MOF) were synthesized via a simple solvothermal method followed by the heat treatment. While measured as anode for lithium ion batteries (LIBs), this MnCoOx@RGO nanocomposite exhibit an initial discharge capacity of 1548 mAhg−1 at 100 mAg−1, and an good reversible capacity of 815 mAhg−1 after 150 cycles. The remarkable lithium storage performance of the nanocomposite is attributed to the synergistic interaction between Mn and Co, the mesoporosity structure, and the conductive reduced graphene oxide (RGO) support, which can shorten the difffusion paths of both Li+ and charge carriers and effectively buffer the volume change during the Li+ insertion/extraction process.

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Additional information

Funding

This project is financially supported by Liaoning Provincial Education Department Project (2020FWDF02), Natural Science Foundation of Liaoning (2021-MS-307).

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