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Original Articles

Pressure Induced Mesophases in Side-Chain Polymer Liquid Crystal Revealed by Neutron Diffraction

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Pages 279-285 | Published online: 27 Oct 2006
 

Abstract

We report here pressure studies on a side-chain liquid crystalline polymer which exhibits a reentrant nematic phase at atmospheric pressure. It reveals that the two nematic transitions behave differently.

The N-SAd transition is shifted towards higher transition temperatures whereas the SAd-NRe transition remains invariant with increasing pressure. In the smectic phase, a significant increase of the order parameter and of the correlation length of the smectic layers is observed. The results are obtained using a pressure cell specifically designed for neutron diffraction.

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