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Original Articles

Pretransitional Surface Phenomena in Ferroelectric Liquid Crystals

, , &
Pages 55-65 | Received 31 Mar 1992, Published online: 24 Sep 2006
 

Abstract

Surface ordering in a ferroelectric liquid crystal was studied using ellipsometry. We observed a pretransitional divergence of the correlation length in the smectic A phase, as the smectic A-smectic C* transition was approached. In the isotropic phase, we measured the pretransitional growth of an ordered surface layer near the isotropic-smectic A transition. The observed surface phenomena support the model of a surface electroclinic effect at the smectic A-smectic C* transition in ferroclectric liquid crystals.

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