Abstract
Surface ordering in a ferroelectric liquid crystal was studied using ellipsometry. We observed a pretransitional divergence of the correlation length in the smectic A phase, as the smectic A-smectic C* transition was approached. In the isotropic phase, we measured the pretransitional growth of an ordered surface layer near the isotropic-smectic A transition. The observed surface phenomena support the model of a surface electroclinic effect at the smectic A-smectic C* transition in ferroclectric liquid crystals.